Evidence of active species in CO oxidation catalyzed by highly dispersed supported gold

This paper is a brief review of suggested structures of catalytic sites and reaction mechanisms in CO oxidation catalyzed by highly dispersed supported gold. The review is focused on evidence of the sites, which has been determined primarily by infrared, X-ray absorption, and other spectroscopies, often combined with transmission electron microscopy; theory has also been applied to characterize supported gold catalysts. The literature gives strong evidence of the reaction of oxygen with CO adsorbed on zerovalent gold at low temperature, consistent with the role of such adsorbed CO in the catalytic reaction. There is also strong evidence of the involvement of cationic gold, even isolated single sites, in the catalysis at higher temperatures (e.g., room temperature). Because CO is only weakly adsorbed on zerovalent gold and more strongly adsorbed on cationic gold, it is suggested that the cationic gold sites may be kinetically more significant than the zerovalent gold sites under potentially practical reaction conditions. (C) 2007 Elsevier B.V. All rights reserved.