Journal
TETRAHEDRON-ASYMMETRY
Volume 18, Issue 7, Pages 900-905Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2007.04.001
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Novel calix[4]arene Schiff bases bearing chiral substituents both on the upper and the lower rims have been developed. These chiral receptors exhibit good chiral recognition ability towards alpha-amino acid ester hydrochlorides (up to K-D/K-L = 4.36, Delta Delta G(O) = - 3.65 kJ mol(-1)) in CHCl3. The molecular recognition abilities and enantioselectivities for guests are also discussed from a thermodynamic point of view. (c) 2007 Elsevier Ltd. All rights reserved.
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