Journal
APPLIED SURFACE SCIENCE
Volume 253, Issue 13, Pages 5701-5704Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2006.12.050
Keywords
adsorption enthalpy; hydrogen adsorption; hydrogen storage; infrared spectroscopy; zeolites
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Variable-temperature infrared spectroscopy was used for the thermodynamic studies on the adsorption of hydrogen on the zeolite (Mg,Na)-Y. Adsorption renders the H-H stretching mode infrared active, and simultaneous measurement of IR absorbance and hydrogen equilibrium pressure, over a range of temperature, allowed adsorption enthalpy and entropy to be determined. The standard adsorption enthalpy and entropy resulted to be AH(o) = - 18.2(+/- 0.8) kJ mol(-1) and AS(o) = - 136(+/- 10) J mol(-1) K-1, respectively. The adsorption enthalpy is substantially higher than the hydrogen liquefaction heat, which suggests that magnesium-containing porous materials are potential candidates in the search for suitable adsorbents for reversible hydrogen storage. (C) 2006 Elsevier B.V. All rights reserved.
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