Journal
TETRAHEDRON
Volume 63, Issue 18, Pages 3840-3849Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.02.076
Keywords
chlorin; deuteration; bromination; metalation
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Funding
- NIGMS NIH HHS [R01 GM036238, R01 GM036238-19, R01 GM036238-18, R01 GM036238-20] Funding Source: Medline
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Stable chlorins bearing few or no substituents have been subjected to a variety of reactions including demetalation, magnesium insertion, oxochlorin formation, and bromination followed by Suzuki coupling. The kinetics of deuteration also have been determined for two oxochlorins and a series of chlorins bearing 0, 1, 2, or 3 meso-aryl substituents. (C) 2007 Elsevier Ltd. All rights reserved.
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