Journal
CHEMICAL & PHARMACEUTICAL BULLETIN
Volume 55, Issue 5, Pages 840-842Publisher
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.55.840
Keywords
alpha,alpha-disubstituted amino acid; peptide; helix; conformation; secondary structure
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L-Leu hexapeptide containing a-aminoisobutyric acid (Aib) forms a right-handed (P) 3(10)-helix, whereas that containing cyclic alpha,alpha-disubstituted amino acid Ac(5)c(dOM) assumes a right-handed (P) alpha-helix in the solid state.
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