Journal
JOURNAL OF NATURAL PRODUCTS
Volume 70, Issue 5, Pages 730-735Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np060389p
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Funding
- NIEHS NIH HHS [P50 ES12736, S11 ES011181-04, S11 ES11181, P50 ES012736-039003, P50 ES012736, P30 ES005705-129001, S11 ES011181-049001, P30 ES005705, S11 ES011181] Funding Source: Medline
- PHS HHS [P20 R15569] Funding Source: Medline
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The isolation and structure elucidation of two cyclic peptides, pahayokolides A (1) and B (2), is described. Structural features determined for these compounds include a pendent N-acetyl-N-methyl leucine, both E- and Z-dehydrobutyrines, a homophenylalanine, and an unusual polyhydroxy amino acid that is most likely of mixed polyketide synthase/nonribosomal peptide synthase origin. These peptides were purified from a new species of cyanobacteria of the genus Lyngbya, which was isolated from a periphyton mat from the Florida Everglades.
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