4.7 Article

In situ Raman spectroelectrochemistry of azobenzene monolayers on glassy carbon

Journal

ANALYTICAL AND BIOANALYTICAL CHEMISTRY
Volume 388, Issue 1, Pages 131-134

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s00216-007-1192-4

Keywords

IR spectroscopy/Raman spectroscopy; electroanalytical methods; nanoparticles/nanotechnology

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In situ Raman spectra of chemisorbed azobenzene (AB) monolayers on glassy carbon (GC) electrodes were observed under potentiostatic conditions in acetonitrile (ACN) with tetrabutyl-ammonium tetrafluoroborate (TBA-BF4). The Raman intensities of these spectra were high below -1000 mV, and this is attributed to the change in absorbance of AB on GC. In this paper, we describe chemisorbed AB molecules on GC electrode surfaces under potentiostatic conditions.

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