Metal-Organic Frameworks (MOFs) as Sandwich Coating Cushion for Silicon Anode in Lithium Ion Batteries

A novel metal-organic framework (MOP) sandwich coating method (denoted as MOP-SC) is developed for hybrid Li ion battery electrode preparation, in which the MOP films are casted on the surface of a silicon layer and sandwiched between the active silicon and the separator. The obtained electrodes show improved cycling performance. The areal capacity of the cheap and readily available microsized Si treated with MOF-SC can reach 1700 mu Ah cm(-2) at 265 mu A cm(-2) and maintain at 850 mu Ah cm(-2) after 50 cycles. Beyond the above, the commercial nanosized Si treated by MOP-SC also shows greatly enhanced areal capacity and outstanding cycle stability, 600 mu Ah cm(-2) for 100 cycles without any apparent fading. By virtue of the novel structure prepared by the MOFs, this new MOP-SC structure serves as an efficient protection cushion for the drastic volume change of silicon during charge/discharge cycles. Furthermore, this MOP layer, with large pore volume and high surface area, can adsorb electrolyte and allow faster diffusion of Li+ as evidenced by decreased impedance and improved rate performance.