Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 10, Issue 5, Pages 520-522Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2007.01.014
Keywords
hydrothermal synthesis; polyoxometalates; arsenotungstate; crystal structure
Categories
Ask authors/readers for more resources
A novel dimeric polyoxotungstate, [Cu(2,2'-bpy)(3)](4)H-2[Cu(H2O)(4)(As2W18O62)(2)] (2,2'-bpy=2,2'-bipyridine) (1), has been synthesized hydrothernially and characterized by elemental analysis, IR, ESR, TG-DTA and single-crystal X-ray diffraction. The title compound represents the first example of dimeric arsenotungstate based on Dawson-type polyanions, in which two As-2 W18O626- blocks are linked by one Cu(H2O)(2+)(4) fragment via O-t-Cu-O-1, bridge. (c) 2007 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available