Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 28, Issue 9, Pages 1017-1023Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200700012
Keywords
conjugated polymers; fluorescence; photophysics; self-organization; star polymers
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A series of monodisperse six-arm benzene-cored star oligofluorenes are prepared by a divergent/convergent strategy, starting from the repetitive divergent synthesis of symmetrical ethynyl-bridged oligofluorenes to the convergent Co-catalyzed alkyne cyclotrimerization. The structures of these six-arm molecules are fully characterized. The diameter of the largest molecule SF3 reaches ca. 3 nm. These highly substituted star-shaped oligomers exhibit extremely high fluorescent quantum yields in solution and unexpected red-shifted and broadened emission with fine structure in the film as a result of the formation of stable aggregates.
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