Journal
JOURNAL OF CHROMATOGRAPHY A
Volume 1148, Issue 2, Pages 131-136Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chroma.2007.02.079
Keywords
experimental design; Box-Behnken design; single-drop microextraction; TCA and TBA; wine; matrix effect
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In this paper a new method for the determination of 2,4,6-trichloroanisole (TCA) and 2,4,6-tribromoanisole (TBA) in wine samples is presented. Headspace single-drop microextraction (HS-SDME) was used for the extraction and preconcentration of the analytes, followed by analysis by gas chromatography and electron-capture detection (GC-ECD). The variables affecting extraction efficiency were optimized using fractional factorial experimental and Box-Behnken designs. The external calibration procedure was successfully carried out using a synthetic wine solution and diluted red wine samples. The method was also applied to white wine samples. Excellent detection limits of 8.1 and 6.1 ng L-1 were achieved for TCA and TBA, respectively. Good precision and accuracy were obtained. (C) 2007 Elsevier B.V. All rights reserved.
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