Journal
TETRAHEDRON LETTERS
Volume 48, Issue 19, Pages 3433-3436Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.03.044
Keywords
pi-conjugated system; annulene; metal reduction; silver complex; X-ray crystal structure.
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Syn theses of all/-Z-tribenzo[12]annulenes (1a-c) and Z,Z-tribenzodidehydro[12]annulenes (2a-c) by the reduction of the corresponding tribenzohexadehydro[ I 2]annulenes 3a-c were carried out using a low valent titanium complex generated from Ti(O-iPr)(4) and i-PrMgCl. The unique structure of the first reduction products 2a-c as well as la-c was fully characterized. Complexation of these annulenes with silver(l) ions produces the corresponding silver complexes. Among them, the silver complexes of 2a-c exhibit interesting monomer dimer equilibrium. (c) 2007 Elsevier Ltd. All rights reserved.
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