Journal
ORGANIC LETTERS
Volume 9, Issue 10, Pages 2023-2026Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070618e
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- NIGMS NIH HHS [GM13598] Funding Source: Medline
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The dinuclear zinc catalyst 1a was found to catalyze the addition of nitroalkanes to carbamate-protected imines. This aza-Henry reaction proceeds with high enantioselectivity when various carbamate-protected imines are used. alpha,beta-Unsaturated imines proved to be a particularly useful class of substrate routinely giving the alpha-nitro amine products in high enantiomeric excess.
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