Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 111, Issue 18, Pages 4685-4692Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0671751
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- NCRR NIH HHS [P41RR0954] Funding Source: Medline
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Pairing of a Keggin or Lindqvist polyoxometalate (POM) anion with an appropriate tetraalkylphosphonium cation is shown to yield the first members of a new family of ionic liquids (ILs). Detailed characterization of one of them, an ambient-temperature liquid POM comprising the Lindqvist salt of the trihexyl(tetradecyl) phosphonium cation, by voltammetry, viscometry, conductimetry, and thermal analysis indicates that it exhibits conductivity and viscosity comparable to those of the one previously described inorganic-organic POM-IL hybrid but with substantially improved thermal stability.
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