4.8 Article

Thermal and photochemical racemization of chiral aromatic sulfoxides via the intermediacy of sulfoxide radical cations

Journal

ORGANIC LETTERS
Volume 9, Issue 10, Pages 1939-1942

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol070500y

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Efficient racemization of enantiomerically pure methyl aryl sulfoxides was obtained by N-methylquinolinium tetrafluoborate (NMQ(+)) sensitized photolysis and by one-electron oxidation catalyzed by tris(2,2'-bipyridyl)ruthenium(III) hexafluorophosphate.

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