Journal
ADVANCED MATERIALS
Volume 19, Issue 10, Pages 1397-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200602284
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A Fe-II-based 1D open framework that exhibits room-temperature spin-crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin-transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host-guest properties directly influence the SCO properties.
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