4.4 Article

Efficient syntheses of streptocarpone and (±)-α-dunnione

Journal

TETRAHEDRON LETTERS
Volume 48, Issue 21, Pages 3735-3738

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.03.090

Keywords

alpha-dunnione; streptocarpone; naphthoquinone; natural product synthesis; furanonaphthoquinone

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An efficient divergent synthesis of both streptocarpone and racemic alpha-dunnione from lawsone are described. A one-pot, formal [3+2] cyclization to form a furanonaphthoquinone directly provided a common intermediate. (c) 2007 Elsevier Ltd. All rights reserved.

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