Journal
NEW JOURNAL OF PHYSICS
Volume 9, Issue -, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/1367-2630/9/5/143
Keywords
-
Categories
Ask authors/readers for more resources
The electronic structure of highly under-coordinated Rh atoms, namely adatoms and ad-dimers, on homo- metallic surfaces has been probed by combining high-energy resolution core level photoelectron spectroscopy and density functional theory calculations. The Rh3d(5/2) core level shifts are shown to be proportional to the number of Rh nearest-neighbours ( n = 3, 4 and 5). A more refined analysis shows that the energy position of the different core level components is correlated with the calculated changes of the individual inter-atomic bond length and to the energy changes of the d-band centre, which is known to be a reliable descriptor of local chemical reactivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available