Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 20, Pages 6394-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja071509y
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A catalytic protocol for the unprecedented enantioselective monofluoromethylation of in situ generated prochiral imines using 1-fluorobis(phenylsulfonyl)methane (FBSM, 1) in the presence of a chiral PTC based on the Mannich-type reaction followed by reductive desulfonylation has been developed.
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