Journal
ORGANIC LETTERS
Volume 9, Issue 11, Pages 2199-2202Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070791a
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- NIGMS NIH HHS [GM066055] Funding Source: Medline
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A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an inverse demand hetero [4 + 2] cycloaddition of a chiral allenamide, and the observation of an unusual urea directed Stork-Crabtree hydrogenation.
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