Journal
ORGANIC LETTERS
Volume 9, Issue 11, Pages 2099-2102Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070507f
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Sulfur ylides stabilized by Ar, vinyl, or amide groups react with five-membered-ring tert-butylsulfinyl aminals to give functionalized chiral, nonracemic aziridines in high yield and with good selectivities ( up to 15:1 trans: cis, up to > 95: 5 trans dr, always > 95:5 cis dr). The intermediate aziridines can be converted into pyrrolidines or piperidines depending on the reaction conditions.
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