Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 11, Pages 4276-4279Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo070181o
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The cycloacylation of aniline derivatives to 4-quinolones in the presence of Eaton's reagent is described. This high-yielding methodology is applicable to a wide variety of functionalized anilines and requires milder conditions than those traditionally employed. This cyclization protocol is used to prepare a host of heterocycles and bis-quinolones and is characterized by relatively low reaction temperature and ease of product isolation.
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