Journal
TETRAHEDRON
Volume 63, Issue 22, Pages 4625-4629Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.03.108
Keywords
cyclopalladated ferrocenylimine; bis(pinacolato)diboron; one-pot borylation; Suzuki cross-coupling
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The cyclopalladated ferrocenylimine was an efficient catalyst for the borylation/Suzuki coupling reaction. The catalytic loading for the reaction containing bromoarenes was 1 mol %. When iodobenzene was used, the catalytic loading was as low as 0.1 mol %. Furthermore, the cyclopalladated ferrocenylimine also exhibited excellent catalytic power in the case of substrates containing electron-donating substituents, with yields reaching 93% or higher. (C) 2007 Elsevier Ltd. All rights reserved.
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