Journal
MACROMOLECULES
Volume 40, Issue 11, Pages 3929-3938Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma062663s
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The first examples of polymers made from the bis-hydrosilylation reaction of 1,3-diynes and bis-silylhydrides are reported. These polymers exhibit modest molecular weights and possess a cis,cis-2,3-disubstituted-1,3-butadiene structure as determined NMR analysis of model compounds. SEC and MALDI analysis of reaction mixtures suggest that cyclic dimers and higher order oligomers are also formed. Model reactions indicate that very sterically hindered diynes or silyl hydrides give only the 1,3-eneyne mono-addition products.
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