Journal
INORGANICA CHIMICA ACTA
Volume 360, Issue 8, Pages 2631-2637Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2006.12.050
Keywords
cadmium(II) halides; 1D polymer; crystal structure; spectroscopic studies; thermal analysis
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Two new one-dimensional coordination polymers have been synthesised by the reaction of cadmium(II) halides with the chelating bidentate ligand, 2-aminomethylpyridine (2-ampy). X-ray single crystal structure analysis shows an octahedral environment around the cadmium atom in the complex, [CdCl2(NC5H4CH2NH2)](n) (1) forming a doubly chloro-bridged polymeric chain, and a rare five-coordinated square-pyramidal geometry in the bromide complex, [CdBr2(NC5H4CH2NH2)](n) (2), which forms an unusual singly bromobridged 1D polymer. Both the complexes have been characterised by elemental analysis, spectroscopic studies and thermal analysis. (C) 2007 Elsevier B.V. All rights reserved.
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