4.3 Article

Selective oxidation and chlorination of trifluoromethylsulfide using trichloroisocyanuric acid in ionic liquid

Journal

JOURNAL OF FLUORINE CHEMISTRY
Volume 128, Issue 6, Pages 636-640

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2007.02.018

Keywords

trifluoromethylsulfide; trifluoromethylsulfoxide; selective oxidation; trichloroisocyanuric acid

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A route to chemoselective oxidation and chlorination of aryltrifluoromethylsulfide using trichloroisocyanuric acid (TCCA) in ionic liquid, an efficiently O-methylation reaction and a reduction of nitro- to amido- in excellent yields have been developed. (c) 2007 Elsevier B.V. All rights reserved.

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