Journal
ANALYTICAL SCIENCES
Volume 26, Issue 6, Pages 671-674Publisher
JAPAN SOC ANALYTICAL CHEMISTRY
DOI: 10.2116/analsci.26.671
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Funding
- National Natural Science Foundation of China [20977026]
- National 863 High Technology Research Foundation of China [2006AA06Z407]
- Research Fund for the Doctoral Program of Higher Education of China [20090161110009]
- Equipment Foundation of Hunan University
- Changjiang Scholars and Innovative Research Team in University (PCSIRT)
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A new fluorescence dye, N-amino-4-(2-hydroxyethylamino)-1,8-naphthalimide (AHN), based on 4-bromo-1,8-naphthalic anhydride was synthesized as a fluorescence probe for determining water content in organic solvents. Changing from a non-polar to a polar solvent increases the solvent interaction with excitation spectrum and emission spectrum shifts to longer wavelengths. The fluorescence intensity of the probe decreased with the increasing concentration of water. In the range of 0.00 - 4.00% (v/v), the AHN fluorescence intensity changed as a linear function of water content. The detection limits were 0.019, 0.038, and 0.060% for dioxane, acetonitrile and ethanol, respectively.
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