Journal
ANALYTICAL SCIENCES
Volume 24, Issue 10, Pages 1347-1349Publisher
JAPAN SOC ANALYTICAL CHEMISTRY
DOI: 10.2116/analsci.24.1347
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [17350037, 19750062]
Ask authors/readers for more resources
Ethylammonium nitrate (EAN) is composed of C2H5NH3+ and NO3- ions, which behave as an acid and a base, respectively. The ionic liquid thus involves small amounts of C2H5NH2 and HNO3 molecules owing to proton transfer from C2H5NH3+ to NO3-. The equilibrium constant K-s (= [C2H5NH2][HNO3]), which corresponds to the autoprotolysis constant of water, was obtained to be ca. 10(-10) mol(2) dm(-6) by potentiometry using an ion-selective field-effect transistor and hydrogen electrodes at 298 K. The value indicates that C2H5NH2 and HNO3 molecules of ca. 10(-5) mol dm(-3) are involved in neat EAN. On the other hand, in an EAN-water mixture, a water molecule behaves as a base. The apparent pK(s) value was determined in EAN-water mixtures of various solvent compositions. Interestingly, the pK(s) value is remained at 10.5 in mixtures over the range of an EAN mole fraction of 0.05 - 0.9. The value is close to the pKa of C2H5NH2, or the acid-dissociation constant of C2H5NH3+, in aqueous solution. This implies that the reaction C2H5NH3+ + H2O -> C2H5NH2 + H3O+ is responsible for the pK(s) over a wide range of solvent composition. The pK(s) value in neat EAN is thus slightly smaller than that in the mixtures, implying that H3O+ is a stronger acid than HNO3 in an EAN solution, unlike water.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available