Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 40, Issue 6, Pages 410-419Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar6000473
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The rapidly growing chemistry of the cations, radicals, and anions based on the group 14 elements heavier than carbon (Si, Ge, Sn, and Pb) is one of the most important organometallic fields. Recent developments in this research area moved such species from the class of short-lived reactive intermediates to the class of easily accessible, isolable, and fully characterizable compounds. In this Account, we deal with the major accomplishments in the field of the stable representatives of heavy cations, radicals, and anions.
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