Journal
ANALYTICAL METHODS
Volume 5, Issue 10, Pages 2497-2502Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ay40284c
Keywords
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Funding
- Faculty of Science of P.J. Safarik University in Kosice [VVGS-PF-2012-25]
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A single-valve sequential injection setup is suggested for automation of an air-assisted liquid-phase microextraction. In order to eliminate parasitic signals, the stopped flow detection mode was employed. The aqueous phase (1.5 mL), containing chromium(VI), chloride ions (0.6 mol L-1), sulphuric acid (0.07 mol L-1) and dimethyl indocarbocyanine dye (1.33 x 10(-4) mol L-1), was dispensed into the extraction chamber and was followed by moderate injection of a 250 mu L organic phase and intense mixing by multiple air bubbling. The extraction phase was then submitted for stopped flow UV-Vis spectrophotometric detection at 560 nm wavelength. The calibration plot was linear up to 104 mu g L-1 of chromium(VI). The limit of detection, calculated as 3s of a blank test (n = 10), was found to be 4.5 mu g L-1. The developed procedure was applied for the determination of Cr(VI) in various water samples.
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