4.4 Article

An efficient metal-catalyzed hydroalkylation

Journal

SYNLETT
Volume -, Issue 9, Pages 1391-1394

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-980363

Keywords

hydroalkylation; hydroarylation; benzylation; bismuth; C-H activation; catalysis; styrene; alkene

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An efficient metal-catalyzed hydroalkylation of various styrenes, norbornene, and cyclohexadiene with 1,3-dicarbonyl compounds has been developed. This new bismuth-catalyzed C-H functionalization provides the corresponding alkylated pentanediones in good to excellent isolated yields after short reaction times.

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