4.6 Article

Rare earth (III) perfluorooctanesulfonates catalyzed synthesis of α-hydroxy-arylacetic acids from aryl methyl ketones in fluorous media

Journal

CATALYSIS COMMUNICATIONS
Volume 8, Issue 6, Pages 871-875

Publisher

ELSEVIER
DOI: 10.1016/j.catcom.2006.08.045

Keywords

alpha-hydroxy-arylacetic acids; fluorous biphasic catalysis; rare earth (III) perfluorooctanesulfonates; perfluorocarbon

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Ytterbiurn perfluorooctanesulfonate (Yb(OPf)(3)) catalyzes the high efficient synthesis of alpha-hydroxy-arylacetic acids from aryl methyl ketones in the presence Of SeO2 in fluorous media. By simple separation, fluorous phase containing only catalyst can be used several times. (c) 2006 Elsevier B.V. All rights reserved.

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