Journal
ADVANCED MATERIALS
Volume 19, Issue 11, Pages 1494-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200700450
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A flexible 3D porous magnet [KCo7(OH)(3)(ip)(6)(H2O)(4)]center dot 12H(2)O based on unprecedented trigonal-prismatic heptanuclear Co-II clusters (see figure) is reported to undergo a reversible single-crystal-to-single-crystal transformation on the desorption/adsorption of guest molecules, accompanied by reversible magnetic property changes. Ibis might be applied for the sensing of coordinative, paramagnetic, small molecules such as 02 and NO.
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