Journal
CHEMISTRY LETTERS
Volume 36, Issue 6, Pages 816-817Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2007.816
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An azo compound based on salicylaldehyde displays a red color upon binding to the cyanide anion with micromolar sensitivity. The high affinity is caused by an intramolecular hydrogen bond of phenol hydrogen to carbonyl oxygen, which stabilizes the anionic character of the intermediate during the nucleophilic attack of a cyanide anion.
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