Journal
INORGANICA CHIMICA ACTA
Volume 360, Issue 9, Pages 3099-3102Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2007.02.010
Keywords
X-ray crystal structures; boronium ions; computational studies; synthesis; boron compounds
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Stable (CF3SO2)(2)N-, I- and BPh4- salts of the boronium ion [(tert-butylamine)(1-methylimidazole)BH2](+) have been isolated and characterized. A single-crystal X-ray structure of the BPh4- salt provides the first unambiguous proof for a boronium ion supported by a primary amine ligand. (c) 2007 Elsevier B.V. All rights reserved.
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