Journal
TETRAHEDRON
Volume 63, Issue 24, Pages 5200-5203Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.03.165
Keywords
palladium; allylation; microwaves; carbon-carbon bond cleavage
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The palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation proceeds at 200-250 degrees C in a toluene-DMF mixed solvent using microwave heating. Even at such high temperatures, the regio- and stereospecificity of the allyl transfer reaction is still satisfactory. The amount of the palladium catalyst can be reduced to 0.5 or 0.05 mol %. (c) 2007 Elsevier Ltd. All rights reserved.
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