Journal
POLYHEDRON
Volume 26, Issue 9-11, Pages 2276-2280Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2006.11.014
Keywords
manganese; clusters; crystal structures; mixed valence; 1,1 '-ferrocenedicarboxylate
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The use of ferrocene-1,1'-dicarboxylic acid (fdcH(2)) in Mn cluster chemistry has led to a family of ferrocene-rich Mn-7, Mn-8 and Mn-13 clusters. The complexes are all mixed-valence. Solid-state DC and AC magnetic susceptibility studies have established the Mn-7, Mn-8 and Mn-13 complexes to possess S = 2, 5 and 9/2 ground states, respectively. (c) 2006 Elsevier Ltd. All rights reserved.
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