4.4 Article

2-nitroso-N-arylanilines:: Products of acid-promoted transformation of σH adducts of arylamines and nitroarenes

Journal

SYNLETT
Volume -, Issue 10, Pages 1525-1528

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-982534

Keywords

nucleophilic; additions; arenes; amines; nitroso group

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Anions generated from arylamines react with substituted nitrobenzenes to form sigma(H) adducts, which, under protonation with acetic acid, undergo transformation to 2-nitroso-N-arylamines, susceptible to reduction, condensation and cyclization reactions.

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