Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 24, Pages 7480-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja071046w
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Funding
- NIH HHS [DP1 OD000285, DP1 OD000285-03] Funding Source: Medline
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This paper describes a new class of homochiral salen-based infinite coordination polymers (ICPs) and the discovery of a novel and pseudo-reversible solvent-induced crystallization process. The solvent, methanol in this case, induces such a transformation through a change in the coordination environment around the metal bridging the metallo-salen portion of the complex. This transformation has allowed us to use X-ray methods to structurally characterize the crystalline product and through spectroscopic comparisons better understand the connectivity and structure of the amorphous ICP particles from which it is derived.
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