Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 111, Issue 24, Pages 6738-6747Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp068774a
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[Fe(bpp)(2)][Pt(ox)(2)]center dot H2O (with bpp = 2,6-bis(pyrazol-3-yl)-pyridine and ox = oxalate) was prepared, and its spin crossover behavior was characterized. The two-step spin transition behavior changes over several cycles. The original behavior is restored when the sample is allowed to relax for a week. Furthermore, the ST exhibits a strong dependence on the heating and cooling rate. Heating the compound at 1 K/min leads to a spin transition with a third step and a second plateau at gamma(HS) approximate to 0.8. Quenching the sample to 77 K also affects the spin transition behavior. The kinetic relaxation is followed after quenching and after light-induced excited spin state trapping experiments.
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