Journal
ANALYTICA CHIMICA ACTA
Volume 594, Issue 1, Pages 52-60Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2007.04.057
Keywords
suspended particulate matter; trace metals; seawater; microwave digestion; flow injection inductively coupled plasma mass spectrometry
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A new technique for the determination of suspended particulate trace metals (P-metals > 0.2 mu m), such as Co, Ni, Cu, Zn, Cd and Pb, in open ocean seawater has been developed by using microwave digestion coupled with flow injection inductively coupled plasma mass spectrometry (FI-ICP-MS). Suspended particulate matter (SPM) was collected from 500 mL of seawater on a Nuclepore filter (0.2 mu m) using a closed filtration system. Both the SPM and filter were completely dissolved by microwave digestion. Reagents for the digestion were evaporated using a clean evaporation system, and the metals were redissolved in 0.8 M HNO3. The solution was diluted with buffer solution to give pH 5.0 and the metals were determined by FI-ICP-MS using a chelating adsorbent of 8-hydroxyquinoline immobilized on fluorinated metal alkoxide glass (MAF-8HQ). The procedure blanks with a filter were found to be 0.048 +/- 0.008, 10.3 +/- 0.3, 0.27 +/- 0.05, 3.3 +/- 1.8, 0.02 +/- 0.03 and 0.85 +/- 0.09 ng L-1 for Co, Ni, Cu, Zn, Cd and Pb, respectively (n = 14). Detection limits defined as 3 times the standard deviation of the blanks were 0.023, 0.90, 0.14, 5.3, 0.078 and 0.28 ng L-1 for Co, Ni, Cu, Zn, Cd and Pb, respectively. Accuracy was evaluated using certified reference materials of chlorella (NES CRM No. 3) and marine sediment (HISS-1). The method was applied to the determination of vertical distributions for P-Co, Ni, Cu, Zn, Cd and Pb in the Western North Pacific. (c) 2007 Elsevier B.V. All rights reserved.
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