Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 25, Pages 7742-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja072718l
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Funding
- NIGMS NIH HHS [GM64444, R01 GM064444] Funding Source: Medline
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The first example of direct C-H alkynylation of electron-rich heteroaromatics has been demonstrated. This mild, simple, and general method allows for the efficient synthesis of diverse alkynyl heterocycles. Kinetic isotope effect studies support an electrophilic substitution pathway for this transformation.
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