4.3 Article Proceedings Paper

Synthesis of new pentafluorosulfanylacrylates (F5SCH=CHCHO, F5SCH=CHCN, F5SCH=CHCOOCH3) and use of them as dienophiles in Diels-Alder reaction

Journal

JOURNAL OF FLUORINE CHEMISTRY
Volume 128, Issue 7, Pages 862-867

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2007.04.013

Keywords

alkenes; Diels-Alder; fluorine; sulfur

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New pentafluoro-lambda(6)-sulfanylacrylates (F5SCH=CHCHO, F5SCH=CHCN, F5SCH=CHCOOCH3) were synthesized by a convenient and efficient method. These compounds are useful as intermediates in the preparation of pentafluoro-lambda 6-sulfanyl-containing cyclic and heterocyclic Diels-Alder cycloadducts. (C) 2007 Elsevier B.V. All rights reserved.

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