Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 9, Issue 7, Pages 1587-1591Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2007.03.004
Keywords
electropolymerization; conducting polymers; polythiophenes; crown ether
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Two crown-annelated bithiophenes in which the external beta-positions are linked together by a polyether chain connected via a sulphide linkage have been synthesized. Preliminary investigations of their electrochemical properties shows that they can be straightforwardly electropolymerized into electroactive functional polythiophenes. A first test of their cation-dependent electrochemical behaviour in the presence of lithium cations is also presented. (C) 2007 Elsevier B.V. All rights reserved.
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