Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 10, Pages 1803-1807Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600636
Keywords
asymmetric hydrogenation; homogeneous catalysis; imidazolium tag; ionic liquids; ligand design; rhodium catalysis
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Josiphos ligands bearing an imidazolium moiety show high efficiency and reusability for the rhodium-catalyzed enantioselective hydrogenation of methyl acetamidoacrylate (MAA) and dimethyl itaconate (DMI) in biphasic co-solvent/ionic liquid combinations.
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