4.7 Article

C5H14NO•ZnCl(HPO3), an unexpected product from an ionic-liquid synthesis

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 10, Issue 7, Pages 833-835

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2007.04.010

Keywords

hybrid solids; ionic liquids; zinc; phosphorus

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C5H14NO center dot ZnCl(HPO3) arose from an unexpected reaction in which a component of the ionic liquid mixed solvent was incorporated into a hybrid structure in which cholinium (C5H14NO+) cations interact with [ZnCl(HPO3)](-) macroanionic layers by way of O-H...O hydrogen bonds. The inorganic layers display a 4 . 8(2) topology. (c) 2007 Elsevier B.V. All rights reserved.

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