Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 10, Pages 1797-1802Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600481
Keywords
asymmetric hydrosilylation; heterogeneous catalysis; nanocrystalline copper(II) oxide; reduction; secondary alcohols
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Asymmetric hydrosilylation of aryl alkyl ketones to afford chiral secondary alcohols with good yields and excellent enantioselectivity is realized by using nanocrystalline copper(II) oxide and BINAP in the presence of organosilanes as the stoichiometric reducing agents.
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