Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 10, Pages 1671-1675Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600525
Keywords
chiral auxiliaries; direct condensation; nanocrystalline magnesium oxide; selectivity; solvent-free conditions; unsymmetrical organic carbonates
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An efficient and selective synthesis of organic carbonates using nanocrystalline magnesium oxide has been realized by the direct condensation of alcohols and diethyl carbonate. The catalyst is quantitatively recovered by simple centrifugation and can be reused for four cycles with almost consistent activity.
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