Journal
ANALYTICAL CHEMISTRY
Volume 83, Issue 9, Pages 3493-3498Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ac200158e
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An accurate and precise measurement of selenium in Standard Reference Material (SRM) 3149, a primary calibration standard for the quantitative determination of selenium, has been accomplished by instrumental neutron activation analysis (INAA) in order to resolve a question arising during the certification process of the standard. Each limiting factor of the uncertainty in the activation analysis, including the sample preparation, irradiation, and gamma-ray spectrometry steps, has been carefully monitored to minimize the uncertainty in the determined mass fraction. Neutron and gamma-ray self-shielding within the elemental selenium INAA standards contributed most significantly to the uncertainty of the measurement. An empirical model compensating for neutron self-shielding and reducing the self-shielding uncertainty was successfully applied to these selenium standards. The mass fraction of selenium in the new lot of SRM 3149 was determined with a relative standard uncertainty of 0.6%.
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