Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 40, Issue 7, Pages 493-500Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar700024g
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Funding
- NIGMS NIH HHS [GM-38767, GM-33162] Funding Source: Medline
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Oxoiron(IV) species are often implicated in the catalytic cycles of oxygen-activating non-heme iron enzymes. The paucity of suitable model complexes stimulated us to fill this void, and our synthetic efforts have afforded a number of oxoiron(IV) complexes. This Account provides a chronological perspective of the observations that contributed to the generation of the first non-heme iron(IV)oxo complexes in high yield and summarizes their salient properties to date.
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